Produktbild: Keynotes in Organic Chemistry
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Keynotes in Organic Chemistry

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Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

26.11.2026

Verlag

Wiley

Seitenzahl

352

Auflage

3. Auflage

Sprache

Englisch

ISBN

978-1-394-34007-1

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

26.11.2026

Verlag

Wiley

Seitenzahl

352

Auflage

3. Auflage

Sprache

Englisch

ISBN

978-1-394-34007-1

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

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  • Produktbild: Keynotes in Organic Chemistry
  • Preface
    Statement on Use of AI

    Chapter 1. Structure and Bonding
    1.1 Ionic versus covalent bonds
    1.2 The octet rule
    1.3 Formal charge
    1.4 Sigma (s-) and pi (¿-) bonds
    1.5 Hybridisation
    1.6 Inductive effects, hyperconjugation and mesomeric effects
    1.7 Acidity and basicity

    Chapter 2. Functional Groups, Nomenclature and Drawing Organic Compounds
    2.1 Functional groups
    2.2 Alkyl and aryl groups
    2.3 Alkyl substitution
    2.4 Naming carbon chains
    2.5 Drawing organic structures

    Chapter 3. Stereochemistry
    3.1 Isomerism
    3.2 Conformational isomers
    3.3 Configurational isomers

    Chapter 4. Reactivity and Mechanism
    4.1 Reactive intermediates: ions versus radicals
    4.2 Nucleophiles and electrophiles
    4.3 Carbocations, carbanions and carbon radicals
    4.4 Steric effects
    4.5 Oxidation levels
    4.6 General types of reaction
    4.7 Ions versus radicals
    4.8 Reaction selectivity
    4.9 Reaction thermodynamics and kinetics
    4.10 Orbital overlap and energy
    4.11 Guidelines for drawing reaction mechanisms

    Chapter 5. Halogenoalkanes
    5.1 Structure
    5.2 Preparation
    5.3 Reactions

    Chapter 6. Alkenes and Alkynes
    6.1 Structure
    6.2 Alkenes
    6.3 Alkynes

    Chapter 7. Benzenes
    7.1 Structure
    7.2 Reactions
    7.3 Reactivity of substituted benzenes
    7.4 Nucleophilic aromatic substitution (the SNAr mechanism)
    7.5 The formation of benzyne
    7.6 Transformation of side chains
    7.7 Reduction of the benzene ring
    7.8 The synthesis of substituted benzenes
    7.9 Electrophilic substitution of naphthalene
    7.10 Electrophilic substitution of pyridine
    7.11 Electrophilic substitution of pyrrole, furan and thiophene

    Chapter 8. Carbonyl Compounds: Aldehydes and Ketones
    8.1 Structure
    8.2 Reactivity
    8.3 Nucleophilic addition reactions
    8.4 a-Substitution reactions
    8.5 Carbonyl-carbonyl condensation reactions

    Chapter 9. Carbonyl Compounds: Carboxylic Acids and Derivatives
    9.1 Structure
    9.2 Reactivity
    9.3 Nucleophilic acyl substitution reactions
    9.4 Nucleophilic substitution reactions of carboxylic acids
    9.5 Nucleophilic substitution reactions of acyl (acid) chlorides
    9.6 Nucleophilic substitution reactions of acid anhydrides
    9.7 Nucleophilic substitution reactions of esters
    9.8 Nucleophilic substitution and reduction reactions of amides
    9.9 Nucleophilic addition reactions of nitriles
    9.10 a-Substitution reactions of carboxylic acids
    9.11 Carbonyl-carbonyl condensation reactions
    9.12 A summary of carbonyl reactivity

    Chapter 10. Spectroscopy
    10.1 Mass spectrometry (MS)
    10.2 The electromagnetic spectrum
    10.3 Ultraviolet (UV) spectroscopy
    10.4 Infrared (IR) spectroscopy
    10.5 Nuclear magnetic resonance (NMR) spectroscopy

    Chapter 11. Natural Products and Synthetic Polymers
    11.1 Carbohydrates
    11.2 Lipids
    11.3 Amino acids, peptides and proteins
    11.4 Nucleic acids
    11.5 Synthetic polymers

    Chapter 12. Synoptic Problems
    12.1 Tips for tackling synoptic problems
    12.2 The synthesis of cetirizine
    12.3 The biosynthesis of limonene
    12.4 Retrosynthetic analysis and paracetamol synthesis
    12.5 Green industrial synthesis of ibuprofen via the BHC process
    12.6 Using a chiral auxiliary in the enantioselective synthesis of (+)-fislatifolione

    Outline Answers
    Further Reading
    Appendix 1. Bond dissociation enthalpies
    Appendix 2. Bond lengths
    Appendix 3. Approximate pKa values (relative to water)
    Appendix 4. Useful abbreviations
    Appendix 5. Infrared absorptions
    Appendix 6. Approximate NMR chemical shifts
    Appendix 7. Key reactions of major functional groups
    Appendix 8. Glossary
    Index