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Produktbild: Organic Synthesis Using Transition Metals

Organic Synthesis Using Transition Metals

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Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

13.04.2012

Verlag

John Wiley & Sons

Seitenzahl

464

Maße (L/B/H)

25,2/19,2/2,5 cm

Gewicht

774 g

Auflage

2. Auflage

Sprache

Englisch

ISBN

978-1-119-97893-0

Beschreibung

Rezension

"In conclusion, this is an outstanding book which should be of value to all process chemists, as well as to postgraduate students." (Organic Process Research & Development Journal, 1 April 2013)

"This fine work, which includes an excellent bibliography, in the field of catalysis will be useful for professional chemists; it also will be a valuable resource for graduate students. Highly recommended. Graduate students, researchers/faculty, and professionals/practitioners." (Choice, 1 December 2012)

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

13.04.2012

Verlag

John Wiley & Sons

Seitenzahl

464

Maße (L/B/H)

25,2/19,2/2,5 cm

Gewicht

774 g

Auflage

2. Auflage

Sprache

Englisch

ISBN

978-1-119-97893-0

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

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  • Produktbild: Organic Synthesis Using Transition Metals

  • About the Author xiii

    Preface xv

    1 Introduction 1

    1.1 The Basics 2

    1.2 The Basic Structural Types 2

    1.3 Just How Many Ligands Can Fit around a Metal Atom? 10

    1.4 Mechanism and the Basic Reaction Steps 13

    1.5 Catalysis 17

    References 19

    2 Coupling Reactions 21

    2.1 Carbon-Carbon Bond Formation 21

    2.2 Lithium and Magnesium: Kumada Coupling 27

    2.3 Zinc: The Negishi Reaction 32

    2.4 Aluminium and Zirconium 35

    2.5 Tin: The Stille Reaction 37

    2.6 Boron: The Suzuki Reaction 46

    2.7 Silicon: The Hiyama Reaction 57

    2.8 Copper: The Sonogashira Reaction 61

    2.9 Other Metals 67

    2.10 Homocoupling 67

    2.11 Enolate and Phenoxide Coupling 69

    2.12 Heteroatom Coupling 70

    References 82

    3 C-H Activation 89

    3.1 Arenes and Heteroarenes 91

    3.2 Aldehydes 100

    3.3 Borylation and Silylation 102

    3.4 Allylic Functionalization 103

    3.5 Unfunctionalized C-H Bonds 105

    References 115

    4 Carbonylation 117

    4.1 Carbonylative Coupling Reactions: Synthesis of Carbonyl Derivatives 117

    4.2 Carbonylative Coupling Reactions: Synthesis of Carboxylic Acid Derivatives 122

    4.3 Carbonylation of Alkenes and Alkynes 127

    4.4 Hydroformylation 130

    4.5 Stoichiometric Carbonylation Using Carbonyl Complexes 139

    4.6 Carboxylation 146

    4.7 Decarbonylation and Decarboxylation 148

    References 150

    5 Alkene and Alkyne Insertion Reactions 153

    5.1 The Heck Reaction 153

    5.2 Insertion Reactions Involving Zirconium and Titanium 175

    References 188

    6 Electrophilic Alkene and Alkyne Complexes 191

    6.1 Electrophilic Palladium Complexes 191

    6.2 Other Metals: Silver, Gold, Platinum and Rare Earths 210

    6.3 Iron 229

    6.4 Cobaloxime _-Cations 235

    References 237

    7 Reactions of Alkyne Complexes 241

    7.1 Alkyne Cobalt Complexes 241

    7.2 Propargyl Cations: The Nicholas Reaction 244

    7.3 The Pauson-Khand Reaction 246

    7.4 Synthesis Using Multiple Cobalt Reactions 250

    References 251

    8 Carbene Complexes 253

    8.1 Fischer Carbenes 253

    8.2 Vinylidene Complexes 269

    8.3 Metathesis Reactions Involving Carbene Complexes 273

    8.4 Carbyne Complexes 310

    8.5 Carbene Complexes from Diazo Compounds 312

    References 319

    9 ¿3- or ¿-Allyl Complexes 325

    9.1 Stoichiometric Reactions of ¿-Allyl Complexes 325

    9.2 Catalysis: Mostly Palladium 328

    9.3 Propargyl Compounds 357

    References 357

    10 Diene, Dienyl and Arene Complexes 361

    10.1 ¿4-Diene Complexes 361

    10.2 ¿5-Dienyl Complexes 371

    10.3 ¿6-Arene Complexes 377

    10.4 ¿2-Arene Complexes 387

    References 389

    11 Cycloaddition and Cycloisomerization Reactions 391

    11.1 Formal Six-Electron, Six-Atom Cycloadditions 391

    11.2 Cycloadditions Involving Fewer than Six Atoms 402

    11.3 Cycloadditions Involving More than Six Atoms 407

    11.4 Isomerization 414

    11.5 Cycloisomerization and Related Reactions 415

    References 426

    Abbreviations 431

    Index of Principle Transition Metal Catalysts and Reagents 433

    Index 437