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Produktbild: Chiral Ferrocenes in Asymmetric Catalysis
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Chiral Ferrocenes in Asymmetric Catalysis Synthesis and Applications

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

16.12.2009

Abbildungen

100

Herausgeber

Li-Xin Dai + weitere

Verlag

Wiley-VCH

Seitenzahl

431

Maße (L/B/H)

2,4/17/24 cm

Gewicht

934 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-3-527-32280-0

Beschreibung

Rezension

"This book might stand out as a landmark summary that marks the sunset of an intense area of research." ( JACS , 2010)

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

16.12.2009

Abbildungen

100

Herausgeber

Verlag

Wiley-VCH

Seitenzahl

431

Maße (L/B/H)

2,4/17/24 cm

Gewicht

934 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-3-527-32280-0

Herstelleradresse

Wiley-VCH GmbH
product_safety@wiley.com
Wiley-VCH GmbH, Boschstrasse 12, DE-69469 Weinheim

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  • Produktbild: Chiral Ferrocenes in Asymmetric Catalysis
  • INTRODUCTION
    Foreword
    Planar Chirality of Ferrocenyl Ligands
    Derivatization of the Ferrocene Scaffold
    Stability, Rigidity and Bulkiness of the Ferrocene Scaffold
    Outlook
    STEREOSELECTIVE SYNTHESIS OF PLANAR CHIRAL FERROCENES
    Introduction
    Diastereoselective Directed Ortho-Metalation of Ferrocenes with Chiral Auxiliaries
    Enantioselective Directed Ortho-Metalation of Ferrocenes with Chiral Bases
    Enzymatic and Nonenzymatic Kinetic Resolutions
    Summary and Perspectives
    Selected Experimental Procedures
    MONODENTATE CHIRAL FERROCENYL LIGANDS
    Introduction
    Nickel-Catalyzed Asymmetric Reductive Coupling Reactions
    Copper(I)-Catalyzed Asymmetric Allylic Alkylation Reactions
    Asymmetric Suzuku-Miyaura Reactions
    Addition of Organoaluminum to Aldehydes and Enones
    Asymmetric Nucleophilic Catalysis
    Conclusions and Perspectives
    BIDENTATE 1,2-FERROCENYL DIPHOSPHINE LIGANDS
    Introduction
    Type A, Both PR2 Groups Attached to the Cp Ring
    Type B, One PR2 Group Attached to the Cp Ring, One PR2 Group Attached to the Alpha-Position of the Side Chain
    Type C, One PR2 Group Attached to the Cp Ring, One PR2 Group Attached to the Beta-Position of the Side Chain
    Type D, One PR2 Group Attached to the Cp Ring, One PR2 Group Attached to Other Positions of the Side Chain
    Type E, Both PR2 Groups Attached to Side Chains
    1,2-P,N-BIDENTATE FERROCENYL LIGANDS
    Introduction
    Asymmetric Hydrogenation and Asymmetric Transfer Hydrogenation
    Formation of C-C Bond
    Cycloaddition Reactions
    Miscellaneous Reactions
    Conclusion and Perspectives
    Experimental: Selected Procedures
    N,O-BIDENTATE FERROCENYL LIGANDS
    Introduction
    Addition of Organozinc Reagents to Aldehydes
    Addition to Aldehydes with Boron Reagents
    Other Transformations: Asymmetric Epoxidation

    Conclusion and Perspectives
    Experimental: Selected Procedures
    SYMMETRICAL 1,1'-BIDENTATE FERROCENYL LIGANDS
    Introduction
    Symmetrical 1,1'-Disubstituted Ferrocenyl Ligands
    Symmetrical 1,1',2,2'-Tetrasubstituted Ferrocenyl Ligands
    Analogs of Ferrocenes: Symmetrical 1,1'-Bidentate Ruthenocenyl Ligands
    Conclusion and Perspectives
    Experimental: Selected Procedures
    UNSYMMETRICAL 1,1'-BIDENTATE FERROCENYL LIGANDS
    Introduction
    Palladium-Catalyzed Asymmetric Allylic Substitution Reaction
    Gold or Silver-Catalyzed Asymmetric Aldol Reactions
    Asymmetric Hydrogenation
    Asymmetric Cross-Coupling Reaction
    Asymmetric Heck Reaction
    Miscellaneous
    Conclusion and Perspectives
    Experimental: Selected Procedures
    SULFUR- AND SELENIUM-CONTAINING FERROCENYL LIGANDS

    Introduction
    Asymmetric Allylic Substitution
    Other Asymmetric Palladium-Catalyzed Reactions
    Gold-Catalyzed Reactions
    Asymmetric Reductions
    Asymmetric 1,2- and 1,4-Nucleophilic Addition
    Asymmetric Cycloaddition Reactions
    Asymmetric Nucleophilic Catalysis
    Conclusion and Perspectives
    Experimental: Selected Procedures
    BIFERROCENE LIGANDS
    Introduction
    Trans-Chelating Chiral Bisphosphines: TRAP
    2,2-Bis(diarylphosphino)-1,1-Biferrocenes: BIFEP
    Miscellaneous Biferrocene-Based Chiral Ligands
    Conclusion
    APPLICATIONS OF AZA- AND PHOSPHAFERROCENES AND RELATED COMPOUNDS IN ASYMMETRIC CATALYSIS
    Introduction
    Background on Aza- and Phosphaferrocenes
    Azaferrocenes in Catalysis
    Phosphaferrocenes in Catalysis
    Conclusions
    METALLOCYCLIC FERROCENYL LIGANDS

    Introduction
    Asymmetric Synthesis of Planar Chiral Metallocylic Complexes
    Stoichiometric Synthetic Applications of Scalemic Planar Chiral Metallocyclic Complexes
    Asymmetric Catalysis with Scalemic Planar Chiral Palladocyclic Complexes
    Conclusion
    SHOW CASE OF THE MOST EFFECTIVE CHIRAL FERROCENE LIGANDS IN VARIOUS CATALYTIC REACTIONS
    Asymmetric Allylic Substitution Reactions
    Asymmetric Aldol Reactions
    Asymmetric Cycloaddition Reactions
    Asymmetric Hydrogenation
    Pd-Catalyzed Asymmetric Heck Reaction

    Addition of Organozinc Reagents
    Asymmetric Rearrangement of Allylic Imidates
    Cu-Catalyzed Cyclopropanation
    Coupling Reaction of Vinyl Bromide and 1-Phenylethylzinc Chloride
    Enantioselective Intramolecular Aminopalladation
    Nickel-Catalyzed Asymmetric Three-Component Coupling of Alkynes, Imines, and Organoboron Reagents
    Reactions with Ketenes
    Ring Opening Reaction