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Produktbild: Physical Chemistry for the Chemical and Biological Sciences

Physical Chemistry for the Chemical and Biological Sciences

164,99 €

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

12.05.2000

Verlag

University Science Books

Seitenzahl

1018

Maße (L/B/H)

28/21/5,5 cm

Gewicht

2365 g

Auflage

2000

Sprache

Englisch

ISBN

978-1-891389-06-1

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

12.05.2000

Verlag

University Science Books

Seitenzahl

1018

Maße (L/B/H)

28/21/5,5 cm

Gewicht

2365 g

Auflage

2000

Sprache

Englisch

ISBN

978-1-891389-06-1

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

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  • Produktbild: Physical Chemistry for the Chemical and Biological Sciences

  • Table of ContentsChapter 1 Introduction1.1 Nature of Physical Chemistry1.2 UnitsForcePressureEnergy1.3 Atomic Mass, Molecular Mass, and the Chemical MoleChapter 2 The Gas Laws2.1 Some Basic Definitions2.2 An Operational Definition of Temperature2.3 Boyle's Law2.4 Charles' and Gay-Lussac's Law2.5 Avogadro's Law2.6 The Ideal Gas Equation2.7 Dalton's Law of Partial Pressures2.8 Real GasesThe van der Waals EquationThe Virial Equation of State2.9 Condensation of Gases and the Critical StateChapter 3 Kinetic Theory of Gases3.1 The Model3.2 Pressure of a Gas3.3 Kinetic Energy and Temperature3.4 The Maxwell Distribution Laws3.5 Molecular Collisions and the Mean Free Path3.6 Gas Viscosity3.7 Graham's Laws of Diffusion and Effusion3.8 Equipartition of EnergyAppendix 3.1 Derivation of Equation (3.24)Appendix 3.2 Total and Partial DifferentiationChapter 4 The First Law of Thermodynamics4.1 Work and HeatWorkHeat4.2 The First Law of Thermodynamics4.3 Enthalpy4.4 A Closer Look at Heat Capacities4.5 Gas ExpansionIsothermal ExpansionAdiabatic Expansion4.6 ThermochemistryStandard Enthalpy of FormationDependence of Enthalpy of Reaction on Temperature4.7 Bond Energies and Bond EnthalpiesBond Enthalpy and Bond Dissociation EnthalpyAppendix 4.1 Exact and Inexact DifferentialsChapter 5 The Second Law of Thermodynamics5.1 Spontaneous Processes5.2 EntropyStatistical Definition of EntropyThermodynamic Definition of Entropy5.3 The Carnot Heat EngineThermodynamic EfficiencyThe Entropy FunctionRefrigerators, Air Conditioners, and Heat Pumps5.4 The Second Law of Thermodynamics5.5 Entropy ChangesEntropy Change due to Mixing of Ideal GasesEntropy Change due to Phase TransitionsEntropy Change due to Heating5.6 The Third Law of ThermodynamicsThird-Law or Absolute EntropiesEntropy of Chemical Reactions5.7 Residual EntropyAppendix 5.1 Statements of the Second Law of ThermodynamicsChapter 6 Gibbs and Helmholtz Energies and Their Applications6.1 Gibbs and Helmholtz Energies6.2 Meaning of Helmholtz and Gibbs EnergiesHelmholtz EnergyGibbs Energy6.3 Standard Molar Gibbs Energy of Formation (ÆfG°)6.4 Dependence of Gibbs Energy on Temperature and PressureDependence of G on TemperatureDependence of G on Pressure6.5 Gibbs Energy and Phase EquilibriaThe Clapeyron and Clausius-Clapeyron EquationsPhase DiagramsThe Phase Rule6.6 Thermodynamics of Rubber ElasticityAppendix 6.1 Some Thermodynamic RelationshipsAppendix 6.2 Derivation of the Phase RuleChapter 7 Nonelectrolyte Solutions7.1 Concentration UnitsPercent by WeightMole fraction (x)Molarity (M)Molality (m)7.2 Partial Molar QuantitiesPartial Molar VolumePartial Molar Gibbs Energy7.3 The Thermodynamics of Mixing7.4 Binary Mixtures of Volatile Liquids7.5 Real SolutionsThe Solvent ComponentThe Solute Component7.6 Phase Equilibria of Two-Component SystemsDistillationSolid-Liquid Equilibria7.7 Colligative PropertiesVapor-Pressure LoweringBoiling-Point ElevationFreezing-Point DepressionOsmotic PressureChapter 8 Electrolyte Solutions8.1 Electrical Conduction in SolutionSome Basic DefinitionsDegree of DissociationIonic MobilityApplications of Conductance Measurements8.2 A Molecular View of the Solution Process8.3 Thermodynamics of Ions in SolutionEnthalpy, Entropy, and Gibbs Energy of Formation of Ions in Solution8.4 Ionic Activity8.5 Debye-Huckel Theory of ElectrolytesThe Salting-In and Salting-Out Effects8.6 Colligative Properties of Electrolyte SolutionsThe Donnan Effect8.7 Biological MembranesMembrane TransportAppendix 8.1 Notes on ElectrostaticsAppendix 8.2 The Donnan Effect Involving Proteins Bearing Multiple ChargesChapter 9 Chemical Equilibrium9.1 Chemical Equilibrium in Gaseous SystemsIdeal GasesReal Gases9.2 Reactions in Solution9.3 Heterogeneous Equilibria9.4 The Influence of Temperature, Pressure, and Catalysts on the Equilibrium ConstantThe Effect of TemperatureThe Effect of PressureThe Effect of a Catalyst9.5 Binding of Ligands and Metal Ions to MacromoleculesOne Binding Site per Macromoleculen Equivalent Binding Sites per MacromoleculeEquilibrium Dialysis9.6 BioenergeticsThe Standard State in BiochemistryATP - The Currency of EnergyPrinciples of Coupled ReactionsGlycolysisSome Limitations of ThermodynamicsAppendix 9.1 The Relationship Between Fugacity and PressureAppendix 9.2 The Relationships Between K1 and K2 and the Intrinsic Dissociation Constant KChapter 10 Electrochemistry10.1 Electrochemical Cells10.2 Single-Electrode Potential10.3 Thermodynamics of Electrochemical CellsThe Nernst EquationTemperature Dependence of EMF10.4 Types of ElectrodesMetal ElectrodesGas ElectrodesMetal-Insoluble Salt ElectrodesGas ElectrodesThe Glass ElectrodeIon-Selective Electrodes10.5 Types of Electrochemical CellsConcentration CellsFuel Cells10.6 Applications of EMF MeasurementsDetermination of Activity CoefficientsDetermination of pH10.7 Potentiometric Titration of Redox Reactions10.8 Biological OxidationThe Chemiosmotic Theory of Oxidative Phosphorylation10.9 Membrane PotentialThe Goldman EquationThe Action PotentialChapter 11 Acids and Bases11.1 Definitions of Acids and Bases11.2 Dissociation of Acids and BasesThe Ion Product of Water and the pH scaleThe Relationship Between the Dissociation Constant of An Acid and Its Conjugate Base11.3 Salt Hydrolysis11.4 Acid-Base TitrationsAcid-Base Indicators11.5 Diprotic and Polyprotic Acids11.6 Amino AcidsDissociation of Amino AcidsIsoelectric Point11.7 Buffer SolutionsEffect of Ionic Strength and Temperature on Buffer SolutionsPreparing a Buffer Solution With a Specific pHBuffer Capacity11.8 Maintaining the pH of BloodAppendix 11.1 A More Exact Treatment of Acid-Base EquilibriaChapter 12 Chemical Kinetics12.1 Reaction Rate12.2 Reaction OrderZero-Order ReactionsFirst-Order ReactionsSecond-Order ReactionsDetermination of Reaction Order12.3 Molecularity of a ReactionUnimolecular ReactionsBimolecular ReactionsTermolecular Reactions12.4 More Complex ReactionsReversible ReactionsConsecutive ReactionsChain Reactions12.5 Effect of Temperature on Reaction RatesThe Arrhenius Equation12.6 Potential-Energy Surfaces12.7 Theories of Reaction RatesCollision TheoryTransition-State TheoryThermodynamic Formulation of the Transition-State Theory12.8 Isotope Effects in Chemical Reactions12.9 Reactions in Solution12.10 Fast Reactions in SolutionThe Flow MethodThe Relaxation Method12.10 Oscillating ReactionsAppendix 12.1 Derivation of Equation (12.9)Appendix 12.2 Derivation of Equation (12.38)Chapter 13 Enzyme Kinetics13.1 General Principles of CatalysisEnzyme Catalysis13.2 The Equations of Enzyme KineticsMichaelis-Menten KineticsSteady-State KineticsThe Significance of KM and Vmax13.3 Chymotrypsin: A Case Study13.4 Multisubstrate SystemsThe Sequential MechanismThe Nonsequential or "Ping-Pong" Mechanism13.5 Enzyme InhibitionReversible InhibitionIrreversible Inhibitions13.6 Allosteric InteractionsOxygen Binding to Myoglobin and HemoglobinThe Hill EquationThe Concerted ModelThe Sequential ModelConformational Changes in Hemoglobin Induced by Oxygen Binding13.7 pH Effects on Enzyme KineticsAppendix 13.1 Kinetic Analysis of the Hydrolysis of p-Nitrophenyl Trimethylacetate Catalyzed by ChymotrypsinAppendix 13.2 Derivations of Equations (13.17) and (13.19)Appendix 13.3 Derivation of Equation (13.32)Chapter 14 Quantum Mechanics14.1 The Wave Theory of Light14.2 Planck's Quantum Theory14.3 The Photoelectric Effect14.4 Bohr's Theory of Hydrogen Emission Spectra14.5 de Broglie's Postulate14.6 The Heisenberg Uncertainty Principle14.7 The Schrodinger Wave Equation14.8 Particle in a One Dimensional BoxElectronic Spectra of Polyenes14.9 Quantum-Mechanical Tunneling14.10 The Schrodinger Wave Equation for the Hydrogen AtomAtomic Orbitals14.11 Many-Electron Atoms and the Periodic TableElectron ConfigurationsVariations in Periodic PropertiesChapter 15 The Chemical Bond15.1 Lewis Structures15.2 Valence Bond Theory15.3 Hybridization of Atomic OrbitalsMethane (CH4)Ethylene (C2H4)Acetylene (C2H2)15.4 Electronegativity and Dipole MomentsElectronegativityDipole Moment15.5 Molecular Orbital Theory15.6 Diatomic MoleculesHomonuclear Diatomic Molecules of the Second-Period ElementsHeteronuclear Diatomic Molecules of the First and Second-Period Elements15.7 Resonance and Electron DelocalizationThe Peptide Bond15.8 Coordination CompoundsCrystal Field TheoryMolecular Orbital TheoryValence Bond Theory15.9 Coordination Compounds in Biological SystemsChapter 16 Intermolecular Forces16.1 Intermolecular Interactions16.2 The Ionic Bond16.3 Types of Intermolecular ForcesDipole-Dipole InteractionIon-Dipole InteractionIon-Induced Dipole and Dipole-Induced Dipole InteractionsDispersion or London InteractionsRepulsive and Total InteractionsThe Role of Dispersion Forces in Sickle-Cell Anemia16.4 The Hydrogen Bond16.5 Structure and Properties of WaterStructure of IceStructure of WaterSome Physiochemical Properties of Water16.4 The Hydrophobic InteractionChapter 17 Spectroscopy17.1 VocabularyAbsorption and EmissionUnitsRegions of the SpectrumLine WidthResolutionIntensitySelection RulesSignal-to-Noise RatioThe Beer-Lambert Law17.2 Microwave Spectroscopy17.3 Infrared SpectroscopySimultaneous Vibrational and Rotational Transitions17.4 Electronic SpectroscopyOrganic MoleculesTransition Metal ComplexesMolecules that Undergo Charge-Transfer InteractionsApplication of the Beer-Lambert Law17.5 Nuclear Magnetic Resonance SpectroscopyThe Boltzmann DistributionChemical ShiftsSpin-Spin CouplingNMR and Rate ProcessesNMR of Nuclei Other Than 1H17.6 Electron Spin Resonance Spectroscopy17.7 Fluorescence and PhosphorescenceFluorescencePhosphorescence17.8 LasersProperties and Applications of Laser LightAppendix 17.1 Fourier-Transform SpectroscopyChapter 18 Molecular Symmetry and Optical Activity18.1 Symmetry of MoleculesProper Rotation AxisPlane of SymmetryCenter of SymmetryImproper Rotation AxisMolecular Symmetry and Dipole MomentMolecular Symmetry and Optical Activity18.2 Polarized Light and Optical Rotation18.3 Optical Rotatory Dispersion and Circular DichroismChapter 19 Photochemistry and Photobiology19.1 IntroductionThermal versus Photochemical ReactionsPrimary versus Secondary ProcessesQuantum YieldsMeasurement of Light IntensityAction Spectrum19.2 Earth's AtmosphereComposition of the AtmosphereRegions of the AtmosphereResidence Time19.3 The Greenhouse Effect19.4 Photochemical SmogFormation of Nitrogen OxidesFormation of O3 • Formation of Hydroxyl RadicalFormation of Other Secondary PollutantsHarmful Effects and Prevention of Photochemical Smog19.5 The Essential Role of Ozone in the StratosphereFormation of the Ozone LayerDestruction of OzonePolar Ozone HolesWays to Curb Ozone Depletion19.6 PhotosynthesisThe ChloroplastChlorophyll and Other Pigment MoleculesThe Reaction CenterPhotosystems I and IIDark Reactions19.7 VisionStructure of RhodopsinMechanism of VisionRotation About the C=C Bond19.8 Biological Effects of RadiationSunlight and Skin CancerLight-Activated DrugsChapter 20 The Solid State20.1 Classification of Crystal Systems20.2 The Bragg Equation20.3 Structural Determination by X-ray DiffractionThe Powder MethodDetermination of the Crystal Structure of NaClThe Structure FactorNeutron Diffraction20.4 Types of CrystalsMetallic CrystalsIonic CrystalsCovalent CrystalsMolecular CrystalsAppendix 20.1 Derivation of Equation (20.3)Chapter 21 The Liquid State21.1 Structure of Liquids21.2 Viscosity21.3 Surface TensionThe Capillary-Rise MethodSurface Tension in the Lungs21.4 DiffusionFick's Laws of Diffusion21.5 Liquid CrystalsThermotropic Liquid CrystalsLyotropic Liquid CrystalsAppendix 21.1 Derivation of Equation (21.13)Chapter 22 Macromolecules22.1 Methods for Determining the Size, Shape, and Molar Mass of MacromoleculesMolar Mass of MacromoleculesSedimentation in the UltracentrifugeViscosityElectrophoresis22.2 Structure of Synthetic PolymersConfiguration and ConformationThe Random-Walk Model22.3 Structure of Proteins and DNAProteinsDNA22.4 Protein StabilityThe Hydrophobic InteractionDenaturationProtein FoldingAppendix 22.1 DNA FingerprintingChapter 23 Statistical Thermodynamics23.1 Macrostates and Microstates23.2 The Boltzmann Distribution Law23.3 The Partition Function23.4 Molecular Partition FunctionTranslational Partition FunctionRotational Partition FunctionVibrational Partition FunctionElectronic Partition Function23.5 Thermodynamic Quantities from Partition FunctionsInternal Energy and Heat CapacityEntropy23.6 Chemical Equilibrium23.7 Transition-State TheoryAppendix 23.1 Justification of Q = qN/N! for Indistinguishable ParticlesAppendicesA. Review of Mathematics and PhysicsB. Thermodynamic DataGlossaryAnswers to Even-Numbered Numerical ProblemsIndex